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Abstract Radium‐226(226Ra) and barium (Ba) exhibit similar chemical behaviors and distributions in the marine environment, serving as valuable tracers of water masses, ocean mixing, and productivity. Despite their similar distributions, these elements originate from distinct sources and undergo disparate biogeochemical cycles, which might complicate the use of these tracers. In this study, we investigate these processes by analyzing a full‐depth ocean section of226Ra activities (T1/2 = 1,600 years) and barium concentrations obtained from samples collected along the US GEOTRACES GP15 Pacific Meridional Transect during September–November 2018, spanning from Alaska to Tahiti. We find that surface waters possess low levels of226Ra and Ba due to export of sinking particulates, surpassing inputs from the continental margins. In contrast, deep waters have higher226Ra activities and Ba concentrations due to inputs from particle regeneration and sedimentary sources, with226Ra inputs primarily resulting from the decay of230Th in sediments. Further, dissolved226Ra and Ba exhibit a strong correlation along the GP15 section. To elucidate the drivers of the correlation, we used a water mass analysis, enabling us to quantify the influence of water mass mixing relative to non‐conservative processes. While a significant fraction of each element's distribution can be explained by conservative mixing, a considerable fraction cannot. The balance is driven using non‐conservative processes, such as sedimentary, rivers, or hydrothermal inputs, uptake and export by particles, and particle remineralization. Our study demonstrates the utility of226Ra and Ba as valuable biogeochemical tracers for understanding ocean processes, while shedding light on conservative and myriad non‐conservative processes that shape their respective distributions.more » « less
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Cochran, J_Kirk; Wei, Ziran; Horowitz, Evan; Fitzgerald, Patrick; Heilbrun, Christina; Stephens, Mark; Lam, Phoebe_J; Le_Roy, Emilie; Charette, Matthew (, Global Biogeochemical Cycles)Abstract Distributions of the natural radionuclide210Po and its grandparent210Pb along the GP15 Pacific Meridional Transect provide information on scavenging rates of reactive chemical species throughout the water column and fluxes of particulate organic carbon (POC) from the primary production zone (PPZ).210Pb is in excess of its grandparent226Ra in the upper 400–700 m due to the atmospheric flux of210Pb. Mid‐water210Pb/226Ra activity ratios are close to radioactive equilibrium (1.0) north of ∼20°N, indicating slow scavenging, but deficiencies at stations near and south of the equator suggest more rapid scavenging associated with a “particle veil” located at the equator and hydrothermal processes at the East Pacific Rise. Scavenging of210Pb and210Po is evident in the bottom 500–1,000 m at most stations due to enhanced removal in the nepheloid layer. Deficits in the PPZ of210Po (relative to210Pb) and210Pb (relative to226Ra decay and the210Pb atmospheric flux), together with POC concentrations and particulate210Po and210Pb activities, are used to calculate export fluxes of POC from the PPZ.210Po‐derived POC fluxes on large (>51 μm) particles range from 15.5 ± 1.3 mmol C/m2/d to 1.5 ± 0.2 mmol C/m2/d and are highest in the Subarctic North Pacific;210Pb‐derived fluxes range from 6.7 ± 1.8 mmol C/m2/d to 0.2 ± 0.1 mmol C/m2/d. Both210Po‐ and210Pb‐derived POC fluxes are greater than those calculated using the234Th proxy, possibly due to different integration times of the radionuclides, considering their different radioactive mean‐lives and scavenging mean residence times.more » « less
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